
Limestone Sulfide and Sulfate Content

Mine water treatment with limestone for sulfate removal
2012年4月1日 Limestone can be an option for sulfate sorption, particularly from neutral mine drainages because calcium ions on the solid surface can bind sulfate ions This work 2014年5月1日 In this study, limestone soil and yellow soil were used as representative soil samples of karst areas in southwest China to analyze the contents and δ 34 S values of total S, organic S, sulfate S (SO 42− –S), and Speciation and Isotopic Composition of Sulfur in 2009年1月1日 The results show that the main impact of limestone additions on resistance to sulfate degradation are physical — ie addition of a few percent in Portland cement reduces Influence of limestone on sulfate ingression ResearchGate2023年3月17日 However, Chating stands out as showing exceptionally high sulfate content, greatly in excess of coeval sulfide We contend that the sulfate anomaly at Chating reflects Melt inclusion evidence for limestone assimilation, calcsilicate

The Use of Limestone as a Strategy to Remove Sulphate from
Sulphate sorption on limestone might be a costeffective alternative to treat mine waters with sulphate concentrations below the values set by gypsum solubility (15002000mg/L) and for This study explores the underlying mechanisms behind the varying grain size distribution of limestone and sulfate requirement in Limestone Calcined Clay Cements (LC 3) on the effects Limestone particle sizes and sulfate impact on the early hydration Over the temperature rang investigated the limiting sulfide solubility isw hin 001 to 003 pct S, whereas the ulfate solubility isw hin 003 to 01 pct S, increasing with increasing temperature Sulfide and sulfate solid solubility in lime, magnesia, and calcined Sulfate concentrations are often much higher in thermal springs than in nonthermal springs, so an analysis of flow processes in aquifers with thermal springs may help underHigh sulfate concentrations in limestone springs: An important
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Mine water treatment with limestone for sulfate removal
2012年4月1日 In most countries, sulfate concentrations in industrial effluents are set from 250 to 500 mg/l to protect the environment In humans, prolonged consumption of water containing 500750 mg/l sulfate 2023年3月17日 Immiscibility seems to have promoted concentration of reduced sulfur in the calcsilicate melt, because sulfide minerals are found mostly in the calcsilicate inclusions that lack anhydrite The most likely redox couple for sulfate reduction is by oxidizing Fe 2+ to Fe 3+, represented by andradite, aegirine, and hematite in the melt inclusionsMelt inclusion evidence for limestone assimilation, calcsilicate Sulfide and Sulfate Solid Solubility in Lime, Magnesia, LIMESTONE invariably contains some sulfur, pri mum sulfur content of burnt lime used in oxygen steel making is about 003 pct, particular attention must be paid to the desulfurization during calcination of the limestone Recently this subject was studied by WriedtSulfide and sulfate solid solubility in lime, magnesia, and calcined 2004年5月1日 Tests for total sulfate The total sulfate content (also referred to as the acid soluble content, AS) is of key importance to soil stabilisation as it gives a measure of the 'reservoir' of sulfates available to react with lime and/or cement, and therefore (in the absence of pyrite) gives an indication of the likely magnitude of ground expansionAssessment of sulfatebearing ground for soil stabilisation for

Sulfate resistance of portlandlimestone cement concrete systems
2020年7月30日 As many detailed reviews have indicated, the incorporation of limestone in amounts greater than about 10–15% will generally worsen the performance of a neat cement, nonsulfate resistant system [1], [2] exposed to external sulfates In addition, upon exposure to sulfate solutions at low temperatures, increasing limestone contents of nonsulfate resistant 2024年7月1日 Despite the great potential of sulfurbased autotrophic denitrification, an improvement in nitrate removal rate is still needed This study used the desulfurized products of Mn ore to develop the MnSS 0limestone autotrophic denitrification system (MSLAD)The feasibility of MSLAD for denitrification was explored and the possible mechanism was proposedManganese sulfidesulfur and limestone autotrophic 2012年6月30日 Highlights Limestone can effectively be applied for sulfate removal from neutral mine drainages Breakthrough curves can be modeled by The BDST and other models Fixedbed loading (194 mg/g) is close to the equilibrium concentration (237 mg/g) Column sorption seems to be film controlled FTIR suggested the presence of sulfate on limestone surfaceMine water treatment with limestone for sulfate removalAnhydrous Sulfates anhydrite CaSO 4 barite BaSO 4 celestite SrSO 4 anglesite PbSO 4 Hydrous Sulfates gypsum CaSO 4 •2H 2 O chalcanthite CuSO 4 •5H 2 O epsomite MgSO 4 •7H 2 O antlerite Cu 3 SO 4 •(OH) 4 alunite KAl 3 (SO 4) 2 (OH) 6 Mineralogists divide sulfate minerals into two groups: the anhydrous sulfates and the hydrous sulfates149: Sulfate Minerals Geosciences LibreTexts
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THAUMASITE SULFATE ATTACK: CASE STUDIES AND IMPLICATIONS
2015年5月3日 There was found to be an decrease in pyrite content and an increase in acidsoluble sulfate as the Lower Lias Clay weathered The amount of pyrite lost in the Made Ground was generally found to be 2012年5月30日 Sulfate originated from gypsum has high δ 34 S and SO 4 2− values Sample G14 come from limestone aquifer containing gypsum in Triassic strata, and showed the highest δ 34 S values Sulfate originated from oxidation of sulfide mineral (pyrite) in sulfurenriched coal often shows significantly low δ 34 S values and high SO 4 2− concentrationHydrogeochemistry and possible sulfate sources in karst Moderate Sulfate Resistance (HS) High Sulfate Resistance Example: ASTM C150 Type II ≈ ASTM C 595 Type IL (MS) – in terms of sulfate resistance How much limestone is in Portland Limestone Cement? PLC may contain anywhere from 5% to 15% limestone CEMEX Type IL typically contains about 10% to 12% limestonePortland Limestone Cement: Frequently Asked Questions2017年12月4日 One possible option is to develop passive and semipassive treatment systems that rely on the anaerobic transformation of sulfate for its removal as hydrogen sulfide or metal sulfides(PDF) SULFATE REMOVAL IN BIOCHEMICAL

Design, application, and microbiome of sulfatereducing bioreactors
2020年6月18日 Sulfatereducing bioreactors, also called biochemical reactors, represent a promising option for passive treatment of mininginfluenced water (MIW) based on similar technology to aerobic/anaerobicconstructed wetlands and verticalflow wetlands MIW from each mine site has a variety of sitespecific properties related to its treatment; therefore, design Generally, sulfate ions are highly soluble in water, except calcium sulfate, strontium sulfate, and barium sulfate These sulfates are poorly soluble in water; Sulfate ions form a white residue\The sulfate ion also acts as a ligand, binding the oxygen atoms together; Uses of Sulfate Sulfuric acid containing sulfate ions is used in leadacid Difference between Sulfate, Sulfite and Sulfide Unacademy2024年7月1日 Despite the great potential of sulfurbased autotrophic denitrification, an improvement in nitrate removal rate is still needed This study used the desulfurized products of Mn ore to develop the MnSS 0limestone autotrophic denitrification system (MSLAD)The feasibility of MSLAD for denitrification was explored and the possible mechanism was proposedManganese sulfidesulfur and limestone autotrophic Sulfide minerals such as pyrite form under reducing conditions in the presence of organic matter Jarosite and natrojarosite, Febearing sulfate minerals, are good indicator minerals Visual observation of morphology and crystal habit is often sufficient to identify many of the carbonate, sulfate, and halide mineralsCarbonate, Halide, Sulfate, and Sulfide Minerals

Source and genesis of Chapai carbonatehosted ZnPb deposit,
2024年1月1日 Carbonatehosted ZnPb deposits are widely distributed all over the world (Heijlen et al, 2003, Leach et al, 2010, Powell and MacQueen, 1984, Sverjensky, 1981, Zaw et al, 2007)The ZnPb deposits occurring in carbonate rocks from late Ediacaran to Early Permian in Sichuan–Yunnan–Guizhou (SYG) provinces, such as Huize, Maozu and Tianbaoshan 2020年8月10日 Supplementary cementitious materials (SCMs) are studied as key materials to reduce clinker (CK)/cement ratio and consequently the CO 2 emission associated with CK production Thus, the sustainability of the industry and the supply of building materials are guaranteed for the long term [1]Among different SCMs, calcined clays are some of the most Influence of calcined clay/limestone, sulfate and clinker Semantic Scholar extracted view of "Manganese sulfidesulfur and limestone autotrophic denitrification system for deep and efficient nitrate removal: Feasibility, performance and mechanism" by Yaqian Li et alManganese sulfidesulfur and limestone autotrophic 2013年1月1日 We analyzed the contents of total sulfur (S), organic S, SO 42S, total reduced inorganic S (TRIS), and sulfatereducing bacteria (SRB) groups and quantities in limestone soil and yellow soil to Distributions of sulfur forms and sulfatereducing bacteria in
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Sulfur Origin and Influences of Water Level Variation
2013年12月31日 The model demonstrates that 76% of initial sulfate is reduced at maximum, and that reduced content is up to 485 mg/L after sulfide oxidation in the NEOB aquifer system Read more Article2023年1月1日 The AMD wastewater moves through the organic layer and limestone bed vertically and is released by the drainage system The lowermost organic layer in sulfatereducing bacteria can change sulfate (SO 4 2−) into hydrogen sulfide (H 2 S) and decompose organic material (–CH 2 O–) into bicarbonate ions (HCO 3 −) (Ayangbenro et al, 2018)Remediation technologies for acid mine drainage: Recent trends 2012年11月1日 The sulfate attack resistance of portlandlimestone cements (PLCs) has been questioned due to their high limestone content, which has the potential to initiate a rare type of sulfate attack that Thaumasite form of sulfate attack in limestone cement concrete: 2019年10月24日 Sulfatereducing bacteria (SRB) are a widespread group of microorganisms that are often isolated from the anoxygenic environments (lake depths, soil, or swamps), and they are also present in the human and animal intestines This group is often detected in patients with inflammatory bowel disease, including ulcerative colitis That is why new rapid methods for Isolation and Purification of SulfateReducing Bacteria

Chapter 3 (Multiple Choice Flashcards Quizlet
Study with Quizlet and memorize flashcards containing terms like 26 Which of the following are all examples of minerals? a bronze, steel, glass, aluminum, pencil lead b gold, silver, uranium, lead, calcium, iron c copper, ice, quartz, topaz, diamond, corundum d water, mercury, metallic hydrogen, limestone e petroleum, coal, iron, feldspar, basalt, Covalent bonds differ from ionic 2024年1月1日 Sulfur autotrophic denitrification process was accompanied by the generation of a large number of sulfate and acidity Research has shown that 754 mg of sulfate is generated and 457 mg of alkalinity is consumed (calculated as CaCO 3) for every 1 mg of NO 3 −N removal [5]The pH and alkalinity are crucial for denitrification process, and limestone is usually used Microbial community structure characteristics and gene 2023年11月20日 Sulfate is ubiquitous as the main dissolved pollutant in coal mine groundwater (Lefticariu et al, 2017)Its main sources include dissolution of sulfate rock, oxidation of sulfide minerals, atmospheric deposition and input of human activities (AlCharideh, 2015)Many scholars have used sulfur and oxygen isotopes to trace the main source of sulfate in groundwater A multiple isotope (S, H, O and C) approach to estimate sulfate 2017年10月28日 For information purposes, the high limit value described in standard ASTM C1012 (different exposure conditions) is 01% However, after 200 days, the system containing less calcined clays and limestone LC380 started to expand To mitigate completely the sulfate attack, a minimum content of calcined clay and limestone must be consideredAlkali Silica Reaction and Sulfate Attack: Expansion of Limestone

Treatment and Control of Acid Mine Drainage ASRS
when alkalinity must be generated by microbial sulfate reduction and limestone dissolution Anoxic limestone drains are buried trenches of limestone that intercept AMD underground to generate alkalinity Under anoxia, limestone should not be coated with Fe+3 hydroxides in the drain, decreasing the likelihood of cloggingE Soilg Eg Emol Eg SOmol Emol SOg SOmol Soilg SOg %311 100 364 1 1254 3 1 96 1 100 30 44 44 ==Ã Ã Ã â ¦(4) Similar stoichiometric calculations were used to determine the concentration of ettringite that can form for a given sulfate content, and these values are presented in Figure 1 as the line labeled â stoichiometryâ Ettringite concentrations predicted to form in these soils THRESHOLD SULFATE LEVELS IN SOILS The National Academies 2014年12月30日 Adjacent ground water, sulfate in concrete, limestone aggregate, and subsoil containing high sulfate content Bickley, 1999 [10] Arctic, Canada: RC column foundations and slabsongrade: Severe deterioration within two years of construction Freeze–thaw action (or low temperature), carbonate aggregates and high sulfate concentration in soilThaumasite sulfate attack on concrete: Mechanisms, influential 2018年5月1日 The limestone was expected to rise pH up to 6 and remove the trivalent metals (Fe(III) and Al) and part of the sulfate, and the barium carbonate was thought to rise pH up to 85 and remove divalent metals and sulfate Since the limestone performance has been previously described in several cases (Ayora et al, 2013 and references therein), only Passive elimination of sulfate and metals from acid mine drainage
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744: Sulfate Minerals Geosciences LibreTexts
Mineralogists have described more than 100 sulfate minerals They fall into two main groups: those that contain water (hydrous sulfates) and those that do not (anhydrous sulfates)Gypsum (CaSO 4 •2H 2 O) is the only common hydrous 2020年4月1日 Anaerobic bacteria present in the depositions generate a large amount of Materials 2021, 14, 5424 2 of 20 hydrogen sulfide gas by reducing sulfate ions (SO 4 2− ) to hydrogen sulfide (H 2 S) in Longterm thaumasite sulfate attack on Portlandlimestone 2011年12月17日 The Sekarna Zn–Pb deposit is located in Central Tunisia at the northeastern edge of the Cenozoic Rohia graben Mineralization comprises two major ore types: (1) disseminated Zn–Pb sulfides that occur as lenses in sedimentary phosphorite layers and (2) cavityfilling zinc oxides (calaminetype ores) that crosscut Late Cretaceous and Early Eocene Phosphoritehosted zinc and lead mineralization in the Springer2020年10月29日 HighResolution Hyperspectral Mineral Mapping: Case Studies in the Edwards Limestone, Texas, USA and SulfideRich Quartz Veins from the Ladakh Batholith, Northern PakistanHighResolution Hyperspectral Mineral Mapping: Case Studies

PortlandLimestone Cements: History, Performance, and
10% limestone Limestone content 5% to 15% AASHTO M240 ASTM C595 Requirements Same physical requirement as existing C595/M240 cement types Chemical requirements – sulfate content, LOI Sulfate resistance – no MS or HS in initial specifications Limestone characteristics– CaCO 3, MBI, TOC IP IS (L) IT(L≥S)2004年1月1日 tated iron sulfide at a rate of sulfate removal of 14 mg/L/day over a 3 (after additi on of lime/limestone) for sulfate re LE 1972 A report on the reducti on of the sulfate content of A review of sulfate removal options for mine waters ResearchGate2017年10月14日 Treatment of acid mine drainage (AMD) highly rich in sulfate and multiple metal elements has been investigated in a continuous flow column experiment using organic and inorganic reactive media Treatment substrates that composed of spent mushroom compost (SMC), limestone, activated sludge and woodchips were incorporated into bacterial sulfate Coupled physicochemical and bacterial reduction mechanisms for 2018年1月1日 Sulfate minerals are mineral species in which the dominant anionic entity is the sulfate anion, [SO 4] 2− (Chang et al 1996; Alpers et al 2000)About 380 valid species of sulfate minerals had been described by early 2017 (cf mindat), which are often grouped into a broader “sulfate” anion class along with the much small number (ca 50) of chromates, Sulfate Minerals SpringerLink